Stereoselective synthesis of enediynes and enynes by condensation of aldehydes with γ-(trialkylsilyl)allenylboranes

DOI: 10.1016/S0040-4039(00)61341-2

Source and publish data:

Tetrahedron Letters p. 8391 - 8394 (1993)

Update date:2022-09-26

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Authors:

Wang Wang

Yu Gui Gu

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Article abstract of DOI:10.1016/S0040-4039(00)61341-2

Enediynes and enynes with high geometric purity were synthesized by treating acetylenic and simple aldehydes with γ-(tert- butyldimethylsilyl)allenylborane 2a followed by the elimination step of the Peterson olefination reaction.

Full text of DOI:10.1016/S0040-4039(00)61341-2

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