Cobalt-catalyzed asymmetric addition of silylacetylenes to 1,1-disubstituted allenes

DOI: 10.1021/jo401604n

Source and publish data:

Journal of Organic Chemistry p. 8986 - 8993 (2013)

Update date:2022-08-05

Topics:

Authors:

Sawano, Takahiro

Ou, Keiyu

Nishimura, Takahiro

Hayashi, Tamio

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Article abstract of DOI:10.1021/jo401604n

The asymmetric addition of silylacetylenes to 1,1-disubstituted allenes proceeded in the presence of a cobalt/chiral bisphosphine ligand to give the corresponding enynes with high enantioselectivity. The results of deuterium-labeling experiments indicated

Full text of DOI:10.1021/jo401604n

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