2-Lithio-2-trimethylsilyl-1-silacyclopentane as a Synthetic Equivalent of 1-Lithio-1,4-butanediol

DOI: 10.1246/cl.1992.2139

Source and publish data:

Chemistry Letters p. 2139 - 2140 (1992)

Update date:2022-08-02

Topics:

Authors:

Matsumoto, Kozo

Yokoo, Toshiaki

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1246/cl.1992.2139

Addition of alkyl iodide to 2-lithio-2-trimethylsilyl-1-silacyclopentane provided 2-alkyl-2-trimethylsilyl-1-silacyclopentane which was converted into 1-alkyl-1,4-butanediol by treatment with H2O2-KF and n-Bu4NF.

Full text of DOI:10.1246/cl.1992.2139

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