Chemical and Pharmaceutical Bulletin p. 2002 - 2006 (1992)
Update date:2022-09-26
Topics:
Ishii
Ishikawa
Takeda
Suzuki
Harayaya
By taking advantage of our novel synthetic methods involving CsF-mediated Claisen rearrangement of an aryl propargyl ether to a 2-methylbenzolfuran and oxidative cleavage of the furan ring to a salicylaldehyde, total synthesis of chelerythrine, a benzo[c]phenanthridine alkaloid, was accomplished via the common intermediate (5) prepared through the two routes shown in Chart 3.
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Doi:10.1021/jo01288a002
(1967)Doi:10.1055/s-2001-17437
(2001)Doi:10.1021/ol800659z
(2008)Doi:10.1016/j.bmc.2008.12.040
(2009)Doi:10.3390/12050979
(2007)Doi:10.1055/s-2008-1032160
(2008)
