Reactions of 1,2-dihalocycloalkenes with alkali metals in presence of chlorotrimethylsilane. Reductive carbon-carbon bond cleavage in five membered homocyclic system

DOI: 10.1016/S0040-4020(01)90165-6

Source and publish data:

Tetrahedron p. 3387 - 3396 (1993)

Update date:2022-08-04

Topics:

Authors:

HariPrasad

Nagendrappa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)90165-6

1,2-Dihalocyclopentenes on reaction with alkali metals and chlorotrimethylsilane in hydrocarbon or ether solvents produce silylated 1-pentynes by ring opening. Sodium metal and hydrocarbon solvents favour the cleavage most. Different mechanistic aspects are considered.

Full text of DOI:10.1016/S0040-4020(01)90165-6

Products guided by the article

Product name:Silane, 1-cyclopenten-1-yltrimethyl-

Cas No:14579-07-8

R&D Labs maybe for 14579-07-8

Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Jinan Jinguilin Chemical Co.,Ltd

Contact:+86-531-81188412

Address:3rd floor of Torch Building, Huanyuan Rd, City of Jinan
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China

Relevant to this article

Isolation and Characterization of a Cationic 19-Electron Iron(III) Hydride Complex; Electron Transfer Induced Hydride Migration by Carbon Monoxide at an Iron(III) Centre

Doi:10.1039/c39920001602
(1992)
Carbene-9-BBN ring expansions as a route to intramolecular frustrated lewis pairs for CO₂ reduction

Doi:10.1002/chem.201304870
(2014)
Synthesis of new metallomesogens based on 3-ketoesters

Doi:10.1134/S1070363213080148
(2013)
Caffeine gold complex supported on magnetic nanoparticles as a green and high turnover frequency catalyst for room temperature A³ coupling reaction in water

Doi:10.1002/aoc.4760
(2019)
Synthesis, antitubercular and anticancer activity of new Baylis-Hillman adduct-derived N-cinnamyl-substituted isatin derivatives

Doi:10.1007/s00044-013-0787-x
(2014)
Selective synthesis of optically active 3-haloazetidin-2-ones or aziridines by the condensation of various metal enolates of α-haloacetate with a chiral imine

Doi:10.1016/S0040-4039(00)74774-5
(1992)

Article Doi