Tetrahedron p. 3387 - 3396 (1993)
Update date:2022-08-04
Topics:
HariPrasad
Nagendrappa
1,2-Dihalocyclopentenes on reaction with alkali metals and chlorotrimethylsilane in hydrocarbon or ether solvents produce silylated 1-pentynes by ring opening. Sodium metal and hydrocarbon solvents favour the cleavage most. Different mechanistic aspects are considered.
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Doi:10.1039/c39920001602
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(2014)Doi:10.1134/S1070363213080148
(2013)Doi:10.1002/aoc.4760
(2019)Doi:10.1007/s00044-013-0787-x
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