Silane, 1-cyclopenten-1-yltrimethyl-

Base Information

• Chemical Name: Silane, 1-cyclopenten-1-yltrimethyl-
• CAS No.: 14579-07-8
• Molecular Formula: C8H16Si
• Molecular Weight: 140.301
• Mol file: 14579-07-8.mol

Synonyms:1-trimethylsilylcyclopentene;cyclopent-1-en-1-yltrimethylsilane;1-trimethylsilylcyclo-1-pentene;Silane,cyclopentenyltrimethyl;Silane,1-cyclopenten-1-yltrimethyl;cyclopenten-1-yltrimethylsilane;

Chemical Property of Silane, 1-cyclopenten-1-yltrimethyl-

Chemical Property:

• Melting Point: 106-108 °C
• Boiling Point: 144 °C
• PSA: 0.00000
• Density: 0.8115 g/cm3
• LogP: 2.97410

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, 1-cyclopenten-1-yltrimethyl-

There total 2 articles about Silane, 1-cyclopenten-1-yltrimethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1,2-dichloro-cyclopentene (59323-36-3) → 1-trimethylsilyl-1-pentyne (18270-17-2) + 1-(trimethylsilyl)cyclopentene (14579-07-8) + 1,5-Bis-trimethylsilanyl-pent-1-yne (122060-21-3) + 1,2-Bis(trimethylsilyl)cyclopentene

Guidance literature:

With sodium; In diethyl ether; for 50h; Yield given. Further byproducts given. Yields of byproduct given; Heating;

DOI:10.1016/S0040-4020(01)90165-6

Reference yield:

chloro-trimethyl-silane (75-77-4) + 1,2-dichloro-cyclopentene (59323-36-3) → 1-trimethylsilyl-1-pentyne (18270-17-2) + 1-(trimethylsilyl)cyclopentene (14579-07-8) + 1,5-Bis-trimethylsilanyl-pent-1-yne (122060-21-3) + 2-chloro-1-trimethylsilylcyclopentene (122060-22-4) + 1,2-Bis(trimethylsilyl)cyclopentene

Guidance literature:

With sodium; In diethyl ether; at 50 ℃; for 60h; Product distribution; Mechanism; other dihalocyclopentenes; other temperatures, metals and solvents; influence of NaBr; scope and limitation of the reaction;

DOI:10.1016/S0040-4020(01)90165-6

Reference yield: 72.0%

1-(trimethylsilyl)cyclopentene (14579-07-8) → cyclopent-2-enone (930-30-3) + 2-(trimethylsilyl)-2-cyclopentenyl hydroperoxide (156518-14-8)

Guidance literature:

With oxygen; 5,15,10,20-tetraphenylporphyrin; In dichloromethane; at -10 - -5 ℃; for 2.5h; Yields of byproduct given; Irradiation;

DOI:10.1021/jo00091a020

upstream raw materials:

chloro-trimethyl-silane

1,2-dichloro-cyclopentene

Downstream raw materials:

2-ethylthiocyclopentanone

2-(hydroxymethyl)cyclopentanone

cyclopent-2-enone

2-(trimethylsilyl)cyclopent-2-en-1-one