Crystal and Molecular Structure of i2-2,6)3(PMe2Ph)>; a Distorted Six-coordinate Tantalum Dihydride

DOI: 10.1039/c39920001505

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1505 - 1507 (1992)

Update date:2022-08-02

Topics:

Authors:

Visciglio, Valerie M.

Fanwick, Phillip E.

Rothwell, Ian P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001505

Reaction of i2-2,6)3R2> (R = CH2C6H4-4-Me) with H2 in the presence of phosphine ligands (L) leads to the dihydride compounds i2-2,6)3(L)>, the solid-state structure of the PMe2Ph derivative shows a geometry about the metal centre that is severely distorted from octahedral; hydrogenation of aryl-phosphines and other aromatic substrates is catalysed by these dihydride compounds.

Full text of DOI:10.1039/c39920001505

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ta(H)2(P(CH₃)2C₆H₁₁)(OC₆H₃(CH(CH₃)2)2)3

Cas No:146053-94-3

R&D Labs maybe for 146053-94-3

Changzhou naidechemical Co.Ltd

Contact:+86-519-82589807

Address:NO.25,Houyang street,Jintan,Changzhou City
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Shanghai Bosman Industrial Co., Ltd

Contact:86-21-63065878-8006

Address:Rm907, No.1611, North Sichuan Road, Hongkou District, Shanghai, 200080 China
LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING

Relevant to this article

Synthesis and crystal structures of cis- and trans-1-(3′-N,N- dimethylthiocarbamoyl-4′-methoxy)-2-(3″, 4″, 5″-trimethoxyphenyl) ethene

Doi:10.1007/s10870-005-2961-6
(2005)
Copper-Catalyzed Diastereoselective Synthesis of Trifluoromethylated Tetrahydrofurans

Doi:10.1002/adsc.201501166
(2016)
Cyclic sulfates as useful tools in the asymmetric synthesis of 1-aminocyclopropane-1-carboxylic acid derivatives

Doi:10.1016/j.tetasy.2015.09.013
(2015)
Zweikernige Rutheniumcluster mit μ₂-η²-Sulfonatoliganden. Synthese und Molekuelstruktur von Ru2(CO)4<μ₂-η²-OOS(O)Tol>2(PPh3)2

Doi:10.1016/0022-328X(92)83389-Y
(1992)
Iodosobenzene-Triflic Anhydride as an Efficient Promoter for Glycosidation Reaction Using Thioglycosides as Donors

Doi:10.1016/S0040-4039(00)60863-8
(1992)
Doi:10.1021/jo01265a011
(1968)

Article Doi