Crystal and Molecular Structure of i2-2,6)3(PMe2Ph)>; a Distorted Six-coordinate Tantalum Dihydride

DOI: 10.1039/c39920001505

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1505 - 1507 (1992)

Update date:2022-08-02

Topics:

Authors:

Visciglio, Valerie M.

Fanwick, Phillip E.

Rothwell, Ian P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001505

Reaction of i2-2,6)3R2> (R = CH2C6H4-4-Me) with H2 in the presence of phosphine ligands (L) leads to the dihydride compounds i2-2,6)3(L)>, the solid-state structure of the PMe2Ph derivative shows a geometry about the metal centre that is severely distorted from octahedral; hydrogenation of aryl-phosphines and other aromatic substrates is catalysed by these dihydride compounds.

Full text of DOI:10.1039/c39920001505

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Ta(H)2(P(CH₃)2C₆H₁₁)(OC₆H₃(CH(CH₃)2)2)3

Cas No:146053-94-3

R&D Labs maybe for 146053-94-3

Shanxi Tongji Pharmaceuticals Co., Ltd.

Contact:+86-359-3024784

Address:Xikuang South Road, Ruicheng County , Shanxi
Ganzhou Zhongneng Industrial Co.,Ltd.

Contact:+86-7973-396425

Address:Xingcun Road,Xinfeng Industrial Zone,Ganzhou City,Jiangxi Province
Tianjin Dongchang Fine Chemical Industry Co., Ltd.

Contact:+86-22-29894595

Address:Economic Developing Zone, Ji County, Tianjin, China
Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China
Tocopharm Co., Ltd.

Contact:+86-021-6989-5597

Address:No.80 Yichuan Rd., Putuo District,Shanghai,P.R.China

Relevant to this article

Synthesis and crystal structures of cis- and trans-1-(3′-N,N- dimethylthiocarbamoyl-4′-methoxy)-2-(3″, 4″, 5″-trimethoxyphenyl) ethene

Doi:10.1007/s10870-005-2961-6
(2005)
Copper-Catalyzed Diastereoselective Synthesis of Trifluoromethylated Tetrahydrofurans

Doi:10.1002/adsc.201501166
(2016)
Cyclic sulfates as useful tools in the asymmetric synthesis of 1-aminocyclopropane-1-carboxylic acid derivatives

Doi:10.1016/j.tetasy.2015.09.013
(2015)
Zweikernige Rutheniumcluster mit μ₂-η²-Sulfonatoliganden. Synthese und Molekuelstruktur von Ru2(CO)4<μ₂-η²-OOS(O)Tol>2(PPh3)2

Doi:10.1016/0022-328X(92)83389-Y
(1992)
Iodosobenzene-Triflic Anhydride as an Efficient Promoter for Glycosidation Reaction Using Thioglycosides as Donors

Doi:10.1016/S0040-4039(00)60863-8
(1992)
Doi:10.1021/jo01265a011
(1968)

Article Doi