Journal of the American Chemical Society p. 5279 - 5285 (1980)
Update date:2022-08-05
Topics:
Zupancic, Joseph J.
Horn, Keith A.
Schuster, Gary B.
The reaction of phthaloyl peroxide with a variety of compounds capable of reacting as one- or two-electron donors was investigated.The products and the kinetics of these reactions indicate that the rate-limiting step is the transfer of one electron from the reactant to the peroxide.This conclusion was substantiated by investigating these reactions by laser flash photolysis.This study showed conclusively that odd-electron intermediates are formed in the reaction of phthaloyl peroxide with ground- and excited-state electron donors.These reactions may be prototypical of a general class of electron-transfer-initiated transformations.
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