
Tetrahedron Letters p. 1047 - 1050 (1993)
Update date:2022-08-04
Topics:
Hoshi, Hideaki
Ohnuma, Takeshi
Aburaki, Shimpei
Konishi, Masataka
Oki, Toshikazu
A total synthesis of 6,7-dihydroeponemycin 2 was achieved via the epoxide intermediate 8a.Unresolved absolute configuration of the epoxide ring in 2 and eponemycin 1 was determined to be 2R by application of the asymmetric Sharpless epoxidation of 9.
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Doi:10.1021/ja409669r
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(2017)