Novel fragmentation of 3-lithio-3,6-dihydro-1,2-oxazines: Synthesis of 2,5-dihydro-2-furanylamines

DOI: 10.1016/S0040-4039(00)77465-X

Source and publish data:

Tetrahedron Letters p. 961 - 962 (1993)

Update date:2022-08-03

Topics:

Authors:

Desai Desai

Doty Doty

Stephens

Brighty Brighty

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Article abstract of DOI:10.1016/S0040-4039(00)77465-X

N-Cbz or N-Boc protected 3,6-dihydro-1,2-oxazines 1 on treatment with LDA at -78°C undergo a novel rearrangement to provide synthetically useful N-Cbz or N-Boc protected dihydro-2-furanylamines 2.

Full text of DOI:10.1016/S0040-4039(00)77465-X

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Product name:6-(tert-Butyl-dimethyl-silanyloxymethyl)-3,6-dihydro-[1,2]oxazine-2-carboxylic acid benzyl ester

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