The Reaction of Bromo- and Iodo-phosphoranes with Unactivated Coarse Grain Manganese Metal Powder to Yield and n> (X = Br or I) by Insertion of Mn into the P-X Bond. The Crystal Structure of

DOI: 10.1039/DT9930000371

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 371 - 376 (1993)

Update date:2022-08-05

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Authors:

Godfrey, Stephen M.

McAuliffe, Charles A.

Pritchard, Robin G.

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Article abstract of DOI:10.1039/DT9930000371

The novel reaction of crude manganese metal powder with dibromo- and diiodo-phosphoranes, R3PX2, has been studied.Reaction of the phosphoranes R3PI2 (R = phenyl or substituted aryl) with manganese allows insertion of the metal into P-X bonds and gives the

Full text of DOI:10.1039/DT9930000371

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