Stereoselective Synthesis of Vinylcyclopropanes via Palladium-Catalyzed Reactions

DOI: 10.1021/jo00233a023

Source and publish data:

Journal of Organic Chemistry p. 5430 - 5435 (1987)

Update date:2022-08-02

Topics:

Authors:

Baeckvall, J. E.

Vagberg, J. O.

Zercher, C.

Genet, J. P.

Denis, A.

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Article abstract of DOI:10.1021/jo00233a023

Vinylcyclopropanes were synthesized in a stereocontrolled manner from 1-acetoxy-4-chloro-2-alkenes.A stereospecific palladium-catalyzed substitution of the chloro group by dimethyl malonate anion and subsequent palladium-catalyzed cyclization afforded the

Full text of DOI:10.1021/jo00233a023

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