147852-45-7

Upstream product

• 147802-00-4 cis-(1R,4S)-4-Acetoxy-2-cyclohexenyl methyl carbonate 
• 108-59-8 malonic acid dimethyl ester 
• 78776-45-1 cis-2-cyclohexenyl-1,4-diacetate 
• 18424-76-5 sodiodimethylmalonate 
• 82736-39-8 cis-1-acetoxy-4-chlorocyclohex-2-ene 
• 18424-76-5 dimethyl malonate sodium salt 
• 1165952-91-9 cyclohexa-1,3-diene 

Downstream Products

• 97399-13-8 2-[(1S,4R)-4-(Toluene-4-sulfonylamino)-cyclohex-2-enyl]-malonic acid dimethyl ester 
• 104307-70-2 dimethyl (2,4-cyclohexadien-1-yl)malonate 
• 104307-72-4 2-(2,4-cyclohexadienyl)acetic acid methyl ester 
• 109803-00-1 tetramethyl 2,2′-(cyclohex-2-ene-1,4-diyl)-dimalonate 
• 109802-83-7 trans-1,4-bis-(dicarbomethoxymethyl)cyclohex-2-ene 
• 147852-51-5 (S)-2-(2,4-Cyclohexadienyl)acetic acid 
• 147852-49-1 (S)-2-(2,4-Cyclohexadienyl)acetic acid methyl ester 
• 104307-74-6 (2,4-cyclohexadienyl)-acetic acid 
• 132541-11-8 1-(benzyloxycarbonyl)-r-7-<3,4-(methylenedioxy)phenyl>-2,3,c-3a,4,7,c-7a-hexahydroindole 
• 132541-11-8 1-(benzyloxycarbonyl)-r-7-<3,4-(methylenedioxy)phenyl>-2,3,t-3a,4,7,t-7a-hexahydroindole 
• 132541-12-9 1-(benzyloxycarbonyl)-r-7-<3,4-(methylenedioxy)phenyl>-2,3,t-3a,4,5,6,7,t-7a-octahydroindole 
• 132541-08-3 <2-(2,4-cyclohexadienyl)ethyl>ammonium chloride 
• 132541-07-2 1-(2,4-cyclohexadienyl)-2-phthalimidoethane 
• 141612-30-8 2-(2,4-cyclohexadienyl)ethanol 

Relevant academic research and scientific papers

Stereoselective Synthesis of Vinylcyclopropanes via Palladium-Catalyzed Reactions

Vinylcyclopropanes were synthesized in a stereocontrolled manner from 1-acetoxy-4-chloro-2-alkenes.A stereospecific palladium-catalyzed substitution of the chloro group by dimethyl malonate anion and subsequent palladium-catalyzed cyclization afforded the

Palladium-catalyzed substitution of allylic fluorides

As unusual substrates for the Tsuji-Trost allylation reaction, allylic fluorides are responsive to palladiumcatalyzed substitution. Their activity towards this reaction fits in the series OCO2Me>OBz? F? OAc. The classic stereoretention mechanis

Asymmetric allylic alkylation of cycloalkenediol diacetates using a chiral phosphine ligand bearing a carboxyl group

Asymmetric induction in the allylic alkylation of cycloalkenediol diacetates was performed using a chiral alkylphosphine ligand bearing a carboxyl group, 3-(diphenylphosphino)butanoic acid. An increase in enantiomeric excess of the monoalkylated products of cis-cycloalkenediol diacetates was observed through a sequential asymmetric allylic alkylation- kinetic resolution process. (C) 2000 Elsevier Science Ltd.

Enzyme and palladium catalysis as a powerful combination in asymmetric transformations of meso-2-alkene-1,4-diol derivatives. Application to enantiodivergent synthesis of (R)- and (S)-(2,4-cycloalkadienyl)acetic acids

Enzymatic hydrolysis of meso-diacetates cis-1,4-diacetoxy-2-cyclo-hexene (4a) and cis-1,4-diacetoxy-2-cycloheptene (4b) was used to prepare enantiomerically pure (> 98% ee) 4-acetoxy-2-cyclohexenol (5a) and 4-acetoxy-2-cycloheptenol (5b), respectively. Th

STEREOSPECIFIC PALLADIUM-CATALYZED 1,4-ACETOXYCHLORINATION OF 1,3-DIENES

Palladium-catalyzed oxidation of 1,3-dienes in acetic acid in the presence of LiCl and LiOAc produces 1-acetoxy-4-chloro-2-alkenes in high selectivity.The 1,4-adducts were stereo- and regioselectively functionalized.