Difluoroiodomethane: Practical Synthesis and Reaction with Alkenes

DOI: 10.1039/c39940000737

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 737 - 738 (1994)

Update date:2022-07-29

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Authors:

Cao, Pin

Duan, Jian-Xing

Chen, Qing-Yun

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Article abstract of DOI:10.1039/c39940000737

Difluorocarbene precusors 2, FSO2CF2COF, FSO2CF2CO2H, FSO2CF2CO2Me and XCF2CO2M react with KI to give HCF2I 1 in high yields; a smooth reaction of 1 with alkenes or alkynes in the presence of Na2S2O4 gives the difluoromethylated adducts in good yields.

Full text of DOI:10.1039/c39940000737

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