Iterative syn-1,3,5-triol synthesis utilizing the reaction of β-(trimethylsilyl)alkylk phenyl sulphones with oxiranes

DOI: 10.1016/S0957-4166(00)86085-1

Source and publish data:

Tetrahedron Asymmetry p. 399 - 410 (1993)

Update date:2022-09-26

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Authors:

Achmatowicz

Wicha Wicha

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Article abstract of DOI:10.1016/S0957-4166(00)86085-1

Partly protected triols 8a and 8b were synthesised from epoxide 1 using β-trimethylsilyl sulphones 2a and 2a for the chain elongation and the Cardillo procedure for diastereoselective two-step epoxidation of homoallylic alcohols.

Full text of DOI:10.1016/S0957-4166(00)86085-1

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Product name:(3R)-1-O-(t-butyldiphenylsilyl)-3-O-(trimethylsilyl)-1,3-dihydroxy-5-methylhex-5-ene

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