Tetrahedron Letters p. 2235 - 2238 (1993)
Update date:2022-08-05
Topics:
Zheng, Qi
Yang, Youhua
Martin, Arnold R.
The palladium catalyzed cross-coupling reaction between 3-indole boronic acids and vinyl triflates is a good method to introduce vinyl groups into the indole 3-position. The regioselectivity of the enolization of N-substituted-3-piperidones is far greater than previously reported. N-tosyl-3-indole boronic acids can be easily synthesized via mercuration-boronation method.
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(1996)
