THE STEREOSELECTIVE SYNTHESIS OF L-TAGATOSE. AN APPLICATION OF Zn(II) MEDIATED HIGHLY STEREOSELECTIVE ADDITION OF 2-FURYLLITHIUM TO POLYOXYGENATED ALDEHYDE

DOI: 10.1246/cl.1982.1169

Source and publish data:

Chemistry Letters p. 1169 - 1170 (1982)

Update date:2022-08-04

Topics:

Authors:

Mukaiyama, Teruaki

Yuki, Yoichi

Suzuki, Keisuke

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Article abstract of DOI:10.1246/cl.1982.1169

In the presence of ZnBr2, the addition of 2-furyllithium to 4-O-benzyl-2,3-O-isopropylidene-L-threose proceeded in a highly stereoselective manner to afford the anti-adduct, which was further converted to L-tagatose.

Full text of DOI:10.1246/cl.1982.1169

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