Preparation of seven-membered rings by the reaction of cyclopropylcarbene-tungsten and molybdenum complexes with alkynes

DOI: 10.1016/S0040-4020(01)87266-5

Source and publish data:

Tetrahedron p. 5507 - 5530 (1993)

Update date:2022-08-04

Topics:

Authors:

Herndon Herndon

Zora Zora

Patel Patel

Chatterjee

Matasi Matasi

Tumer Tumer

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Article abstract of DOI:10.1016/S0040-4020(01)87266-5

The reaction between alkynes and cyclopropylcabene-tungsten and molybdenum complexes has been examined. Depending upon the conditions of the reaction, either cycloheptadienones of furanones are obtained. The scope, limitation, and mechanistic rationale fo

Full text of DOI:10.1016/S0040-4020(01)87266-5

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