Journal of the Chemical Society. Perkin transactions I p. 2017 - 2026 (1994)
Update date:2022-07-31
Topics:
Shing, Tony K. M.
Tai, Vincent W.-F.
Cyclophellitol 1 and its (1R,6S)-, (2S)-, (1R,2S,6S)-diastereoisomers 2, 3 and 4 are constructed from quinic acid involving the following key steps: regioselective cyclic sulfate ring opening, regiospecific oxidative elimination and an epoxidation.Diastereoisomers 1, 2, 3 and 4 are characterized as their corresponding tetraacetates 5, 6, 7 and 8.
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