Synthesis of butenynylruthenium complexes from hydrido, alkenyl, or alkynyl complexes

DOI: 10.1021/om00034a070

Source and publish data:

Organometallics p. 4215 - 4218 (1993)

Update date:2022-09-26

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Authors:

Santos, Amelia

López, Javier

Matas, Lluisa

Ros, Josep

Galán, Amelia

Echavarren, Antonio M.

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Article abstract of DOI:10.1021/om00034a070

The reaction of Ru(CO)ClH(PPh₃)₃ with 1-alkynes in 1,2-dichloroethane under reflux conditions provides the coordinatively unsaturated butenynyl complexes [Ru{C(C≡CR)=CHR}(CO)Cl(PPh₃)₂] in good yield. These and r

Full text of DOI:10.1021/om00034a070

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Product name:RuHCl(CO)(P(C₆H₅)3)2(C₉NH₇)

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