
Journal of the Chemical Society, Dalton Transactions p. 3163 - 3168 (1993)
Update date:2022-09-26
Topics:
Tattershall, Bruce W.
Kendall, Nigel L.
The hydrides α-P4S4(H)R (R = H, I, NMePh or SPh) have been prepared in solution by the reaction of α-P4S3I2 or of the corresponding α-P4S3(I)R with Sn-n-Bu3H, and identified by 31P NMR spectroscopy.The compounds were unstable and not isolated.Ab initio molecular orbital calculations of geometry have been carried out for α-P4S3H2, α-P4S3(NMe2)2 and α-P4S3H(NMe2).
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