Synthesis and Absolute Stereochemistry of (-)-Protolichesterinic Acid, Antitumor Antibiotic Lactone from Cetraria islandica

DOI: 10.1021/jo00078a037

Source and publish data:

Journal of Organic Chemistry p. 7537 - 7541 (1993)

Update date:2022-08-04

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Authors:

Murta, Maria M.

Azevedo, Mariangela B. M. de

Greene, Andrew E.

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Article abstract of DOI:10.1021/jo00078a037

The first synthesis of (-)-protolichesterinic acid is described.The approach, based on a facially selective 2 + 2 cycloaddition reaction of dichloroketene with an enantiopure O-alkyl enol ether, permits the assignment of the absolute stereochemistry of th

Full text of DOI:10.1021/jo00078a037

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