Stereoselective Construction of Quaternary Centres at Ambient Temperature by the Highly Stereocontrolled Migration of Groups Containing sp-, sp2-, and sp3-Hybridized Carbon Atoms

DOI: 10.1021/jo00074a019

Source and publish data:

Journal of Organic Chemistry p. 5944 - 5951 (1993)

Update date:2022-09-26

Topics:

Authors:

Marson, Charles M.

Walker, Andrew J.

Pickering, Jane

Hobson, Adrian D.

Wrigglesworth, Roger

Edge, Simon J.

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Article abstract of DOI:10.1021/jo00074a019

A very highly diastereoselective semipinacol rearrangement of 2,3-epoxy alcohols mediated by tin(IV) chloride at ambient temperatures is shown to be applicable to a wide variety of migration groups including methyl, tert-butyl, cyclopropyl, vinyl, alkynyl

Full text of DOI:10.1021/jo00074a019

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