Journal of Organic Chemistry p. 5944 - 5951 (1993)
Update date:2022-09-26
Topics:
Marson, Charles M.
Walker, Andrew J.
Pickering, Jane
Hobson, Adrian D.
Wrigglesworth, Roger
Edge, Simon J.
A very highly diastereoselective semipinacol rearrangement of 2,3-epoxy alcohols mediated by tin(IV) chloride at ambient temperatures is shown to be applicable to a wide variety of migration groups including methyl, tert-butyl, cyclopropyl, vinyl, alkynyl
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