Journal of Organometallic Chemistry p. 181 - 188 (1994)
Update date:2022-08-05
Topics:
Lambert, Marie-Pierre
Ratier, Max
Duboudin, Jean-Georges
Petraud, Michel
In the presence of small amounts of p-thiocresol, hydrostannylation of propargyl p-tolyl sulfide promotes the unexpected formation of (Z)-1,2-bis(organostannyl)olefin instead of yielding normal addition products.The application of a non-refocusing INEPT pulse sequence in 119Sn NMR spectroscopy allows the determination of its stereochemistry by comparison of observed patterns with calculated spectra.Key words: Hydrostannylation; Nuclear magnetic resonance; INEPT; Propargyl sulfides
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(1994)
