Journal of Organometallic Chemistry p. 181 - 188 (1994)
Update date:2022-08-05
Topics:
Lambert, Marie-Pierre
Ratier, Max
Duboudin, Jean-Georges
Petraud, Michel
In the presence of small amounts of p-thiocresol, hydrostannylation of propargyl p-tolyl sulfide promotes the unexpected formation of (Z)-1,2-bis(organostannyl)olefin instead of yielding normal addition products.The application of a non-refocusing INEPT pulse sequence in 119Sn NMR spectroscopy allows the determination of its stereochemistry by comparison of observed patterns with calculated spectra.Key words: Hydrostannylation; Nuclear magnetic resonance; INEPT; Propargyl sulfides
Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.
Contact:+86-21-51320130-801, 816
Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
Luojiang Chenming Biological Products Co
Contact:+86 15000297032
Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,
Beijing Wisdom Chemicals Co., Ltd.
Contact:+86-10-52350335
Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Buffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
Shandong Yaroma Perfumery Co., Ltd.
Contact:+86- 531- 88024598
Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Doi:10.1016/0031-9422(81)83047-6
(1981)Doi:10.1016/j.tetlet.2014.01.067
(2014)Doi:10.1055/s-0033-1339923
(2013)Doi:10.1016/j.tetlet.2014.01.121
(2014)Doi:10.1021/om00020a025
(1994)Doi:10.1002/jlcr.2580340606
(1994)
