A novel route to a new lactone intermediate for C-nucleosides via an intramolecular sulfonium ylide rearrangement. A formal synthesis of (+)-showdomycin

DOI: 10.1016/S0040-4039(00)60417-3

Source and publish data:

Tetrahedron Letters p. 7627 - 7628 (1993)

Update date:2022-09-26

Topics:

Authors:

Kim, Guncheol

Kang, Sunwha

Kim, Soon Nam

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Article abstract of DOI:10.1016/S0040-4039(00)60417-3

The lactone of 3,6-anhydro-4,5-O-isopropylidene-2-thiophenoxy-D-allo-heptonic acid was prepared by means of an intramolecular carbenoid-phenylthiofuranose reaction.

Full text of DOI:10.1016/S0040-4039(00)60417-3

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