Tetrahedron Asymmetry p. 2279 - 2282 (1993)
Update date:2022-08-04
Topics:
Roucoux
Agbossou
Mortreux
Petit
Syntheses of new easily accessible chiral alkylarylamidophosphinephosphinite chelating ligands are described. Their rhodium complexes [Rh(L2*)Cl]2 are highly effective precursors for the catalytic asymmetric hydrogenation of functionalized ketones. Ketopantoyllactone and N-benzylphenyl glyoxamide are converted to the corresponding alcohols up to 96 and 79.6% ee respectively.
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Doi:10.1002/ange.202007039
(2020)Doi:10.1134/s1070328408030044
(2008)Doi:10.1002/ardp.19933260904
(1993)Doi:10.1021/ic4025519
(2014)Doi:10.1021/jo00082a030
(1994)Doi:10.1039/b006837n
(2000)