REACTIONS OF POLYFLUOROARYL BROMIDES AND IODIDES WITH C-, Si-, Ge-, Sn- AND Pb-ELECTROPHILES AND TRIS(DIALKYLAMINO)PHOSPHINES

Article abstract of DOI:10.1016/S0022-1139(00)82342-8

The reactions of polyfluoroaryl bromides Ar_FBr or iodides Ar_FI with P(NR'2)3 and R3MX (R = alkyl; M = Si, Ge, Sn and Pb; X = Cl, Br) led to the formation of Ar_FMR3.The reactions of C6F5Br with P(NEt2)3 and C-electrophiles (CH3I, C6F5CF3 and (CF3)2C=CFC2F5) gave the products of pentafluorophenylation of these substrates.