REACTIONS OF POLYFLUOROARYL BROMIDES AND IODIDES WITH C-, Si-, Ge-, Sn- AND Pb-ELECTROPHILES AND TRIS(DIALKYLAMINO)PHOSPHINES

DOI: 10.1016/S0022-1139(00)82342-8

Source and publish data:

Journal of Fluorine Chemistry p. 213 - 231 (1991)

Update date:2022-08-04

Topics:

Authors:

Bardin, V. V.

Pressman, L. S.

Rogoza, L. N.

Furin, G. G.

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Article abstract of DOI:10.1016/S0022-1139(00)82342-8

The reactions of polyfluoroaryl bromides Ar_FBr or iodides Ar_FI with P(NR'2)3 and R3MX (R = alkyl; M = Si, Ge, Sn and Pb; X = Cl, Br) led to the formation of Ar_FMR3.The reactions of C6F5Br with P(NEt2)3 and C-electrophiles (CH3I, C6F5CF3 and (CF3)2C=CFC2F5) gave the products of pentafluorophenylation of these substrates.

Full text of DOI:10.1016/S0022-1139(00)82342-8

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