Advanced Synthesis and Catalysis p. 2293 - 2299 (2016)
Update date:2022-09-26
Topics:
Baars, Hannah
Engel, Julien
Mertens, Lucas
Meister, Daniela
Bolm, Carsten
Carbamoyl fluorides are formed in reactions of hydroxylamines with difluorocarbene generated from sodium bromodifluoroacetate as readily available and non-toxic carbene precursor. The process shows a high functional group tolerance, and the reaction path has been rationalized by computational calculations. (Figure presented.) .
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