Total synthesis of (±)-clavizepine

DOI: 10.1016/S0040-4020(01)81754-3

Source and publish data:

Tetrahedron p. 10215 - 10224 (1994)

Update date:2022-09-26

Topics:

Authors:

Ishibashi, Hiroyuki

Takagaki, Kazutaka

Imada, Noriko

Ikeda, Masazumi

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Article abstract of DOI:10.1016/S0040-4020(01)81754-3

The first total synthesis of benzopyranobenzazepine alkaloid (±)- clavizepine (1) has been achieved by using the Bradsher cyclization of the keto ester 16 (leading to 18) and the Pummerer-type cyclization of the sulfoxide 25 (leading to 26) as the key ste

Full text of DOI:10.1016/S0040-4020(01)81754-3

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