Studies in biomimetic polyether synthesis: Construction of an ABCD-ring subunit of etheromycin using polyepoxide cascade cyclisations

DOI: 10.1016/S0040-4039(00)61619-2

Source and publish data:

Tetrahedron Letters p. 7137 - 7140 (1993)

Update date:2022-07-29

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Authors:

Paterson, Ian

Tillyer, Richard D.

Smaill, Jeff B.

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Article abstract of DOI:10.1016/S0040-4039(00)61619-2

The diepoxides 8 and 9 were prepared by Horner-Emmons and aldol coupling reations from 21 and 13, respectively. The derived β-diketones 22 and 24 were cyclised under acidic conditions to generate the C₁-C₂₂ segment 7, which contains

Full text of DOI:10.1016/S0040-4039(00)61619-2

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