Journal of the Chemical Society, Dalton Transactions p. 885 - 894 (1994)
Update date:2022-07-29
Topics:
Moucheron, Cecile
Dietrich-Buchecker, Christiane O.
Sauvage, Jean-Pierre
Dorsselaer, Alain van
A series of new homo- and hetero-leptic copper(I) complexes have been prepared with various substituted polychelating 1,4,5,8,9,12-hexaazatriphenylene (hat) derivatives.The homoleptic complexes, the stability of which is strongly related to the number and nature of the substituents borne by their two identical acyclic hat ligands, appeared in general less stable than their corresponding heteroleptic complexes prepared with the similar hat acyclic ligand and a macrocycle derived from a 1,10-phenanthroline.The results show clearly that by tethering the first chelate to a macrocycle of adequate size, more stable complexes can be obtained.All the complexes described were characterized by fast bombardment and electrospray mass spectrometry.
ShiJiaZhuang Dowell Chemical Co.,Ltd.
website:http://www.dowechem.com
Contact:+86-13463963265
Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China
Anhui Dexinjia Biopharm Co., Ltd
Contact:+86-531-82375818
Address:9 Hexie Road, kaifaqu, Taihe
Contact:+86-512-56795332
Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
website:http://www.chinacharm.cn/
Contact:86 551 5316260
Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
Chemsigma International Co.,Ltd.
website:http://www.chemsigma.com
Contact:86-025-58748998
Address:Rm.705, 15th Building,Rd.Xinke II
Doi:10.1002/hlca.19970800502
(1997)Doi:10.1002/anie.199718921
(1997)Doi:10.1016/S0040-4020(97)00613-3
(1997)Doi:10.1002/jhet.2703
(2017)Doi:10.1039/c39940001309
(1994)Doi:10.1021/acs.orglett.9b01048
(2019)
