Intramolecular Ring Opening of Epoxides by Bis-Activated Carbanions. The Influence of Ring Size on Reactivity and Selectivity

DOI: 10.1021/jo00085a045

Source and publish data:

Journal of Organic Chemistry p. 1518 - 1524 (1994)

Update date:2022-08-04

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Authors:

Benedetti, Fabio

Berti, Federico

Fabrissin, Silvio

Gianferrara, Teresa

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Article abstract of DOI:10.1021/jo00085a045

A quantitative study on the effect of ring size in the intramolecular ring opening of epoxides by carbanions is described.Two series of substrates were examined: α,α-bis-sulfonyl ω-epoxides 1 and α-cyano-α-sulfonyl ω-epoxides 2; in each series the carbani

Full text of DOI:10.1021/jo00085a045

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