Rearrangement studies on 3,3-bis(methylthio)-1-(arylcyclopropyl) -2-propen-1-ols: Synthesis of functionalized cyclopentenes and polyene esters

DOI: 10.1016/S0040-4020(01)80748-1

Source and publish data:

Tetrahedron p. 255 - 264 (1994)

Update date:2022-08-02

Topics: Synthesis

Authors:

Patro, Balaram

Deb, Bishwajit

Ila, Hiriyakkanavar

Junjappa, Hiriyakkanavar

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Article abstract of DOI:10.1016/S0040-4020(01)80748-1

The cyclopropyl carbinols 8 and 9 obtained by either borohydride reduction (or Grignard addition) of the cyclopropyl ketones 1 are shown to undergo acid induced ring opening and intramolecular cyclization (5-exo or 6-endo) or deprotonation to afford eithe

Full text of DOI:10.1016/S0040-4020(01)80748-1

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