Bulletin of the Chemical Society of Japan p. 1100 - 1106 (1994)
Update date:2022-08-03
Topics:
Ito, Suketaka
Kakehi, Akikazu
Tabata, Keiichi
Thermolyis of aryl azidomethyl ketone N-methyl-N-phenylsulfonylhydrazones gave aryl 4-aryl-2-imidazolyl ketone N-methyl-N-phenylsulfonylhydrazones and arylglyoxal bis(N-methyl-N-phenylsulfonylhydrazone)s, the formation of which can be interpreted in terms of the insertion of nitrene into the α-methylene C-H bond of the original azidomethyl ketone hydrazones and the formation of an azo intermediate from the nitrene precursor, respectively.The structures of these products have been confirmed by an X-ray diffraction method.
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Doi:10.1016/j.tetasy.2013.12.008
(2014)Doi:10.1021/acs.organomet.9b00119
(2019)Doi:10.1021/jo402668q
(2014)Doi:10.1021/ic403077q
(2014)Doi:10.1016/S0040-4039(00)76783-9
(1994)Doi:10.1016/S0040-4039(00)73364-8
(1994)
