Chemical and Pharmaceutical Bulletin p. 489 - 494 (1994)
Update date:2022-08-03
Topics:
Fujita
Wada
Iida
Nishimura
Kanai
Toyama
Three new groups of peptaibols, trichodecenins, trichorovins and trichocellins, have been isolated from conidia of the fungus, Trichoderma viride. The structures of trichodecenins-I and -II were established by positive-ion fast-atom bombardment, collision-induced dissociation mass spectrometry and two-dimensional NMR spectroscopy. Trichodecenins-I and -II have a (Z)-4-decenoyl group, six amino acid residues and a leucinol moiety in the molecules. Trichodecenin-II was synthesized by the solution-phase method.
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(1966)
