Synthesis of β-lactones by the photochemical reactions of chromium alkoxycarbene complexes with aldehydes

DOI: 10.1021/jo00096a047

Source and publish data:

Journal of Organic Chemistry p. 4972 - 4976 (1994)

Update date:2022-08-02

Topics:

Authors:

Colson Colson

Hegedus Hegedus

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Article abstract of DOI:10.1021/jo00096a047

Photolysis of chromium alkoxycarbene complexes with aldehydes in the presence of Lewis acids produced β-lactones in low yield. Incorporation of the aldehyde into either side chain of the carbene complex resulted in intramolecular processes which were considerably more efficient.

Full text of DOI:10.1021/jo00096a047

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