Synthesis of β-lactones by the photochemical reactions of chromium alkoxycarbene complexes with aldehydes

DOI: 10.1021/jo00096a047

Source and publish data:

Journal of Organic Chemistry p. 4972 - 4976 (1994)

Update date:2022-08-02

Topics:

Authors:

Colson Colson

Hegedus Hegedus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00096a047

Photolysis of chromium alkoxycarbene complexes with aldehydes in the presence of Lewis acids produced β-lactones in low yield. Incorporation of the aldehyde into either side chain of the carbene complex resulted in intramolecular processes which were considerably more efficient.

Full text of DOI:10.1021/jo00096a047

Products guided by the article

Product name:(6,6-Bis-benzyloxy-hexyloxy)-tert-butyl-dimethyl-silane

Cas No:157491-73-1

R&D Labs maybe for 157491-73-1

Nowa pharmaceuticals Co., LTD

Contact:86-512-69362780,69362785

Address:No.69 Weixin Road,Weiting Town,Suzhou Industrial Park
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Taizhou KEDE Chemical.Co.,Ltd.

Contact:86-576-84613060

Address:Jiangkou Chemical Zoon
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.

Contact:+86-(574)-81110986

Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China

Relevant to this article

A novel methodology for synthesis of dihydropyrazole derivatives as potential anticancer agents

Doi:10.1039/c3ob42432d
(2014)
Discovery of N-Arylsulfonyl-Indole-2-Carboxamide Derivatives as Potent, Selective, and Orally Bioavailable Fructose-1,6-Bisphosphatase Inhibitors - Design, Synthesis, in Vivo Glucose Lowering Effects, and X-ray Crystal Complex Analysis

Doi:10.1021/acs.jmedchem.0c00726
(2020)
Pd^II-Catalyzed Oxidative Tandem aza-Wacker/Heck Cyclization for the Construction of Fused 5,6-Bicyclic N,O-Heterocycles

Doi:10.1002/asia.201800646
(2018)
Synthesis of α-amino acids by addition of putative azido radicals to α-methoxy acrylonitriles derived from aldehydes and ketones

Doi:10.1016/S0040-4039(00)77143-7
(1994)
Doi:10.1002/hlca.19440270139
(1944)
Lifetimes and UV-visible absorption spectra of benzyl, phenethyl, and cumyl carbocations and corresponding vinyl cations. A laser flash photolysis study

Doi:10.1139/v99-210
(1999)

Article Doi