Synthesis of β-lactones by the photochemical reactions of chromium alkoxycarbene complexes with aldehydes

DOI: 10.1021/jo00096a047

Source and publish data:

Journal of Organic Chemistry p. 4972 - 4976 (1994)

Update date:2022-08-02

Topics:

Authors:

Colson Colson

Hegedus Hegedus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00096a047

Photolysis of chromium alkoxycarbene complexes with aldehydes in the presence of Lewis acids produced β-lactones in low yield. Incorporation of the aldehyde into either side chain of the carbene complex resulted in intramolecular processes which were considerably more efficient.

Full text of DOI:10.1021/jo00096a047

Products guided by the article

Product name:(6,6-Bis-benzyloxy-hexyloxy)-tert-butyl-dimethyl-silane

Cas No:157491-73-1

R&D Labs maybe for 157491-73-1

Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Xi'an yuanfar international trade company

website:https://www.yuanfarchemical.com

Contact:86-029-88745613 ext 828

Address:Floor19th ,B Building, Oak Block,No.36 South Fenghui Road, Dev. Zone of High-Tech Ind.,Xi’an, China
HEZE KINGVOLT CHEMICAL CO., LTD

Contact:86-573-82118911

Address:Juancheng Industry Park
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China

Relevant to this article

A novel methodology for synthesis of dihydropyrazole derivatives as potential anticancer agents

Doi:10.1039/c3ob42432d
(2014)
Discovery of N-Arylsulfonyl-Indole-2-Carboxamide Derivatives as Potent, Selective, and Orally Bioavailable Fructose-1,6-Bisphosphatase Inhibitors - Design, Synthesis, in Vivo Glucose Lowering Effects, and X-ray Crystal Complex Analysis

Doi:10.1021/acs.jmedchem.0c00726
(2020)
Pd^II-Catalyzed Oxidative Tandem aza-Wacker/Heck Cyclization for the Construction of Fused 5,6-Bicyclic N,O-Heterocycles

Doi:10.1002/asia.201800646
(2018)
Synthesis of α-amino acids by addition of putative azido radicals to α-methoxy acrylonitriles derived from aldehydes and ketones

Doi:10.1016/S0040-4039(00)77143-7
(1994)
Doi:10.1002/hlca.19440270139
(1944)
Lifetimes and UV-visible absorption spectra of benzyl, phenethyl, and cumyl carbocations and corresponding vinyl cations. A laser flash photolysis study

Doi:10.1139/v99-210
(1999)

Article Doi