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Structure and Reactions of the Thioether Half-sandwich Ruthenium(II) Complexes aneS3)>2 and aneS3)>2 (aneS3=1,4,7-trithiacyclononane)

DOI: 10.1039/DT9940001885

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1885 - 1894 (1994)

Update date:2022-08-03

Topics:

Authors:

Landgrafe, ClaudiaLandgrafe, Claudia

Sheldrick, William S.Sheldrick, William S.

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Article abstract of DOI:10.1039/DT9940001885

The complex aneS3)>2 2 (<9>aneS3=1,4,7-trithiacyclononane) was prepared by reaction of aneS3)> 1 (dmso=dimethyl sulfoxide) with Ag(CF3SO3) in acetonitrile.It has been employed as a starting material for the synthesis of the mixed-ligand sandwich complexes (<9>aneS3)> 3 (pz=pyrazol-1-yl) and (<9>aneS3)>2 4 and the dinuclear half-sandwich complex <aneS3)>2>2 5.The complex aneS3)>2 6 may likewise be used for the preparation of thioether half-sandwich ruthenium(II) complexes such as aneS3)> 7 and aneS3)> 8 (C7H4NS2=2-sulfanylbenzothiazolate).The structures of 1, 2 and 5-7 have been determined by X-ray crystallography.

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Product name:[Ru(C7H4NS2)(P(C6H5)3)(SC2H4SC2H4SC2H4)](1+)*CF3SO3(1-)=[Ru(C7H4S2N)(P(C6H5)3)(SC2H4SC2H4SC2H4)](CF3SO3)

Cas No:157527-32-7

157527-32-7

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