Structure and Reactions of the Thioether Half-sandwich Ruthenium(II) Complexes aneS3)>2 and aneS3)>2 (aneS3=1,4,7-trithiacyclononane)

DOI: 10.1039/DT9940001885

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1885 - 1894 (1994)

Update date:2022-08-03

Topics:

Authors:

Landgrafe, Claudia

Sheldrick, William S.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9940001885

The complex aneS3)>2 2 (<9>aneS3=1,4,7-trithiacyclononane) was prepared by reaction of aneS3)> 1 (dmso=dimethyl sulfoxide) with Ag(CF3SO3) in acetonitrile.It has been employed as a starting material for the synthesis of the mixed-ligand sandwich complexes (<9>aneS3)> 3 (pz=pyrazol-1-yl) and (<9>aneS3)>2 4 and the dinuclear half-sandwich complex <aneS3)>2>2 5.The complex aneS3)>2 6 may likewise be used for the preparation of thioether half-sandwich ruthenium(II) complexes such as aneS3)> 7 and aneS3)> 8 (C7H4NS2=2-sulfanylbenzothiazolate).The structures of 1, 2 and 5-7 have been determined by X-ray crystallography.

Full text of DOI:10.1039/DT9940001885

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Ru(C₇H₄NS₂)(P(C₆H₅)3)(SC₂H₄SC₂H₄SC₂H₄)]⁽¹⁺⁾*CF₃SO₃^(1-)=[Ru(C₇H₄S₂N)(P(C₆H₅)3)(SC₂H₄SC₂H₄SC₂H₄)](CF₃SO₃)

Cas No:157527-32-7

R&D Labs maybe for 157527-32-7

Nanjing Ruizhi Industry & Technologh Co.，Ltd.

Contact:+86-25-86808110

Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Jiangsu Mingchem Corporation

Contact:0519-85170101-802

Address:Fifth Floor,B of Beihua Buliding,520 Road of Science and Education City,Changwu middle road NO.801,Wujin District,Changzhou,Jiangsu province
Hangzhou utanpharma Co., Ltd

Contact:0571-86821378 ,86820258,56836287,56830923,

Address:Block D ,20F, Tianyuan Building,No.508, Wensan RD, 310013,Hangzhou Zhejiang China
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone

Relevant to this article

Palladium-catalyzed c-2 selective olefination of thiazoles

Doi:10.1021/ol500542j
(2014)
Enhancing the reactivity of nickel(II) in hydrogen evolution reactions (HERs) by β-hydrogenation of porphyrinoid ligands

Doi:10.1039/c7sc02073b
(2017)
Synthesis, characterization, oxygen electrocatalysis and OFET properties of novel mono- and ball-type metallophthalocyanines

Doi:10.1039/c3dt51955d
(2014)
Doi:10.1016/0020-1693(94)03898-8
(1994)
Synthesis and evaluation of 2′-dihalo ribonucleotide prodrugs with activity against hepatitis C virus

Doi:10.1016/j.bmc.2019.115208
(2020)
REACTIVITE DES PERFLUOROHALOGENOALCANES EN PRESENCE DE COUPLES METALLIQUES. REACTIVITE DE PERFLUOROIODOALCANES SUR DES DERIVES HALOGENES DANS DES SOLVANTS APROTIQUES DISSOCIANTS (DMSO, DMF).

Doi:10.1016/S0022-1139(00)82214-9
(1982)

Article Doi