Novel asymmetric desymmetrization of meso-1,2-diols via diastereoselective β-elimination of chiral α-arylsulfinyl acetals

DOI: 10.1016/0040-4020(96)00294-3

Source and publish data:

Tetrahedron p. 6527 - 6546 (1996)

Update date:2022-09-26

Topics:

Authors:

Maezaki, Naoyoshi

Soejima, Motohiro

Takeda, Miwako

Sakamoto, Atsunobu

Matsumori, Yuki

Tanaka, Tetsuaki

Iwata, Chuzo

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Article abstract of DOI:10.1016/0040-4020(96)00294-3

Enantioselective desymmetrization of meso-1,2-diols was accomplished via diastereoselective C-O bond fission of acetals derived from various optically active β-ketosulfoxides with high diastereoselectivities. The substituent at the γ-position of the β-ketosulfoxide plays an important role in this cleavage.

Full text of DOI:10.1016/0040-4020(96)00294-3

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