Tetrahedron p. 6527 - 6546 (1996)
Update date:2022-09-26
Topics:
Maezaki, Naoyoshi
Soejima, Motohiro
Takeda, Miwako
Sakamoto, Atsunobu
Matsumori, Yuki
Tanaka, Tetsuaki
Iwata, Chuzo
Enantioselective desymmetrization of meso-1,2-diols was accomplished via diastereoselective C-O bond fission of acetals derived from various optically active β-ketosulfoxides with high diastereoselectivities. The substituent at the γ-position of the β-ketosulfoxide plays an important role in this cleavage.
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