A new synthesis of 4-thiofuranosides via regioselective opening of an episulfide with allylmagnesium bromide

DOI: 10.1021/jo00095a017

Source and publish data:

Journal of Organic Chemistry p. 4430 - 4432 (1994)

Update date:2022-08-04

Topics: Synthesis Regioselective

Authors:

Branalt Branalt

Kvarnstrom

Svensson

Classon Classon

Samuelsson

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Article abstract of DOI:10.1021/jo00095a017

A new synthesis of 4-thiofuranosides which might be of general interest is described. (2R,3S)-3-[[(4-Bromobenzyl)oxy]methyl]oxirane-2-methanol (1) was converted to the corresponding epithio derivative 2 with inversion of configuration at both chiral cente

Full text of DOI:10.1021/jo00095a017

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