Diastereoselective hetero-Diels-Alder cycloaddition of a C-nitroso compound prepared starting from a homochiral imidazolidin-2-one

DOI: 10.1016/0957-4166(94)80123-1

Source and publish data:

Tetrahedron Asymmetry p. 1535 - 1540 (1994)

Update date:2022-08-03

Topics:

Authors:

Cardillo

Galeazzi

Mobbili Mobbili

Orena Orena

Rossetti

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0957-4166(94)80123-1

By Swern oxidation of the hydroxamic acid 3, prepared from the homichiral imidazolidin-2-one 1, the transient C-nitroso derivative 4 is obtained, and its cycloaddition to either cyclohexadiene or cyclopentadiene proceeds with high diastereoselection, owin

Full text of DOI:10.1016/0957-4166(94)80123-1

Products guided by the article

Product name:(4S,5R)-1-chlorocarbonyl-3,4-dimethyl-5-phenylimidazolidin-2-one

Cas No:158267-01-7

R&D Labs maybe for 158267-01-7

JinTan Pingsheng Chemical Co.,Ltd

Contact:+86-519-82828200

Address:NO.11Danfengxilu Road,Jintan City,Jiangsu,China
Hangzhou innopharma technology Co,.Ltd.(expird)

Contact:+86-13388601988

Address:Room845,lixin building, moganshan road, hangzhou, china
Xi'an Galaxy Chemicals CO., Ltd

Contact:86-29-89380370

Address:No.8, Gaoxin three road, Xi'an city.
DU-HOPE INTERNATIONAL GROUP

Contact:+86-25-52346955

Address:199,JIANYE ROAD,NANJING,CHINA
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China

Relevant to this article

Oxidatively induced M-C bond cleavage reactions of Cp*Ir(Me₂SO)Me₂ and Cp*Rh(Me₂SO)Me₂ (Cp* = η⁵-C₅Me₅)

Doi:10.1039/b107451m
(2002)
Enantioselective synthesis of α-amino acids from N-tosyloxy β-lactams derived from β-keto esters

Doi:10.1021/jo0162437
(2003)
β-Functionalized selenides and tellurides by hydrochalcogenation of olefins containing electron-withdrawing groups

Doi:10.1016/S0040-4039(02)00095-3
(2002)
Action d'un Tetrafluoroborate d'Oxaziridinium sur les Amines et les Imines

Doi:10.1016/S0040-4020(01)89569-7
(1994)
Preparation of hyperbranched aromatic polyimides via A₂ + B₃ approach

Doi:10.1021/ma012113o
(2002)
Intramolecular 4+3 cycloadditions. A cyclohexenyl cation, its halogenated congener and a quasi-Favorskii rearrangement

Doi:10.1016/S0040-4039(02)00264-2
(2002)

Article Doi