Bulletin of the Chemical Society of Japan p. 1943 - 1952 (1997)
Update date:2022-08-05
Topics:
Matsuhashi, Hayao
Asai, Satoshi
Hirabayashi, Kazunori
Hatanaka, Yasuo
Mori, Atsunori
Hiyama, Tamejiro
The cross-coupling reaction of allylic carbonates with organosilanes was found to proceed without fluoride ion activation under mild conditions by using a coordinatively unsaturated palladium complex as a catalyst.The reaction was assumed to proceed through an allylpalladium alkoxide derived from the allylic carbonate substrate and a palladium(0) species, the alkoxo ligand activating the organosilicon reagent.Likewise, diene monoxides also underwent cross-coupling with alkenyl- and arylfluorosilanes in moderate to high yields.
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