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Synthesis and Vibrational Spectra of New Bis(alkoxysulfane)dichloropalladium(II) Complexes and X-Ray Structural Analysis of 2>

DOI: 10.1039/DT9940002509

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2509 - 2514 (1994)

Update date:2022-07-29

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Authors:

Steudel, RalfSteudel, Ralf

Kustos, MonikaKustos, Monika

Schmidt, HeinarSchmidt, Heinar

Wenschuh, EberhardWenschuh, Eberhard

Kersten, MathiasKersten, Mathias

Wloszczynski, AndreaWloszczynski, Andrea

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Article abstract of DOI:10.1039/DT9940002509

Reactions of L = (iPrO)2S, (nPrO)2S, (MeO)(C4H8NO)S (C4H8NO = morpholino), (MeO)(C5H10N)S (C5H10N = piperidino) or (MeO)PhS with in toluene gave five complexes of type (yields 40-79percent).An X-ray structural analysis of the air-stable, monoclinic crystals of 2> showed the sulfur atoms to be cis-planar co-ordinated.The two co-ordinated dialkoxysulfane ligands are rotational isomers with differing SO torsional angles (+79 and 84 deg for ligand 1, -106 and +82 deg for 2).The S-O bond lengths are in the range 1.586 - 1.611 Angstroem.The infrared and Raman spectra of the five complexes demonstrate that the rule of mutual exclusion is not obeyed, indicating a cis rather than a trans co-ordination in each case.

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