Chemical Communications p. 1245 - 1246 (1996)
Update date:2022-09-26
Topics:
Leznoff, Clifford C.
Hu, Mougang
Nolan, Kieran J. M.
Condensation of 4-substituted phthalonitriles with lithium 2-N,N-dimethylaminoethoxide in 2-N,N-dimethylaminoethanol gives a non-statistical mixture of tetrasubstituted phthalocyanines at room temperature or lower while 3-substituted phthalonitriles similarly condense with lithium octan-1-olate in octan-1-ol giving 1,8,15,22-tetra-substituted phthalocyanines as pure isomers.
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