Use of 1,3-dioxin-4-ones and related compounds in synthesis. XLIV. Asymmetric aldol reaction of 4-trimethylsiloxy-6-methylene-1,3-dioxines: Use of tartaric acid-derived (acyloxy)borane complex as the catalyst

DOI: 10.1248/cpb.42.839

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 839 - 845 (1994)

Update date:2022-09-26

Topics:

Authors:

Sato Sato

Sunami Sunami

Sugita Sugita

Kaneko Kaneko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.42.839

A novel enantioselective synthesis of 1,3-dioxin-4-ones having a 2-hydroxylated alkyl group at the 6-position has been accomplished by chiral tartaric acid-derived acylborane-mediated aldol condensation of the silyl enol ether derived from 6-methyl-derivatives of 1,3-dioxin-4-one with achiral aldehydes.

Full text of DOI:10.1248/cpb.42.839

NII-Electronic Library Service

Products guided by the article

Product name:4-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-2-phenyl-ethyl]-1,5-dioxa-spiro[5.5]undec-3-en-2-one

Cas No:158732-52-6

R&D Labs maybe for 158732-52-6

Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
Feiyang Biotechnology Co., Ltd.

Contact:+86-533-7866339

Address:Qilu Chemistry Park, 200m north of Management Community Building of Park
Reliable Pharma Technology (Shanghai) Co., Ltd.

Contact:0086-21-67676847-8008

Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.

Relevant to this article

GADAIN, A LIGNAN FROM JATROPHA GOSSYPIFOLIA

Doi:10.1016/S0031-9422(00)80544-0
(1984)
Synthesis and conformational analysis of chiral ureas incorporating N-1-phenylethyl groups. Manifestation ofallylic 1,3-strain

Doi:10.1002/poc.939
(2005)
Titanocene dihalides and ferrocenes bearing a pendant α-d- xylofuranos-5-yl or α-d-ribofuranos-5-yl moiety. synthesis, characterization, and cytotoxic activity

Doi:10.1021/om500200r
(2014)
Ratiometric fluorescent probe for sensing Streptococcus mutans glucosyltransferase, a key factor in the formation of dental caries

Doi:10.1039/c9cc00440h
(2019)
Synthesis and Evaluation of the Bonding Properties of a Potentially Tridentate Ligand: 1-(Diphenylphosphino)-2-ethoxy-1-(2-pyridyl)ethane

Doi:10.1039/DT9940002755
(1994)
Diacylglycerol lactones targeting the structural features that distinguish the atypical C1 domains of protein kinase C Ζ and ι from typical C1 domains

Doi:10.1021/jm500165n
(2014)

Article Doi