Organometallics of Diphosphazanes. Part 10. Dinuclear Group 6 Metal Carbonyl Complexes bridged by a Cyclodiphosphazane in its cis or trans Form

DOI: 10.1039/DT9940002661

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2661 - 2668 (1994)

Update date:2022-08-04

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Authors:

Reddy, Venkata S.

Krishnamurthy, Setharampattu S.

Nethaji, Munirathinam

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Article abstract of DOI:10.1039/DT9940002661

Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodiphosphazane ligand, 2 (L), have been used as synthons to prepare homo- and hetero-bimetallic complexes in which the cyclodiphosphazane bridges the two metal centres in its cis or trans isomeric forms.The dimolybdenum complex 5-C5H5)2(CO)4(μ-L)> has also been synthesized.The trends in 31P NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed.

Full text of DOI:10.1039/DT9940002661

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