Total Synthesis of (+/-)-Parvifoline and (+/-)-Isoparvifolinone

DOI: 10.1016/0040-4020(95)00517-C

Source and publish data:

Tetrahedron p. 9285 - 9300 (1995)

Update date:2022-08-02

Topics: Asymmetric synthesis NMR spectroscopy Total synthesis X-ray crystallography Diels-Alder Reaction C-H Functionalization

Authors:

Villagomez-Ibarra, Roberto

Alvarez-Cisneros, Celina

Joseph-Nathan, Pedro

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Article abstract of DOI:10.1016/0040-4020(95)00517-C

The total synthesis of the unusual trimethylbenzocyclooctenes (+/-)-parvifoline (1) and (+/-)-isoparvifolinone (5) have been achieved by using the Grob fragmentation reaction of mesylate 25 as the key step.

Full text of DOI:10.1016/0040-4020(95)00517-C

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Product name:2-bromo-4-mesyloxy-5-methylbenzyl bromide

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