Tetrahedron p. 9285 - 9300 (1995)
Update date:2022-08-02
Topics: Asymmetric synthesis NMR spectroscopy Total synthesis X-ray crystallography Diels-Alder Reaction C-H Functionalization
Villagomez-Ibarra, Roberto
Alvarez-Cisneros, Celina
Joseph-Nathan, Pedro
The total synthesis of the unusual trimethylbenzocyclooctenes (+/-)-parvifoline (1) and (+/-)-isoparvifolinone (5) have been achieved by using the Grob fragmentation reaction of mesylate 25 as the key step.
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