Journal of the Chemical Society, Dalton Transactions p. 3377 - 3382 (1994)
Update date:2022-07-30
Topics:
Blake, Alexander J.
Champness, Neil R.
Forder, Robin J.
Frampton, Christopher S.
Frost, Carole A.
et al.
Reaction of RuCl3*3H2O or a trans arrangement of the Cl(1-) ligands with the Ru(II) occupying a crystallographic inversion centre with four precisely coplanar equatorial PPhH2 ligands, Ru-Cl 2.422(3), Ru-P(1) 2.319(3) and Ru-P(2) 2.318(3) Angstroem.The lower steric demands of the PPhH2 ligands compared to PPh2H are reflected in the more regular octahedral arrangement seen in trans-a trans arrangement of two Cl(1-) and four PPh2H ligands, Os(1)-Cl 2.448(2), Os(2)-Cl 2.443(2), Os(1)-P 2.357(2), 2.349(2), Os(2)-P 2.355(2), 2,333(2) Angstroem.With the exception of a reversible oxidation in each case, which is assigned to a M(II)-M(III) redox couple.
TIANJIN NORTH JINHENG CHEMICAL PLANT.
Contact:0086-22-59952083
Address:DongShigu Country In JiXian TianJin China
Buffett (China) Holding Co.,Ltd
Contact:4006570891
Address:
Contact:+86-22-83718541
Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
guide(suzhou) fine materials co. ltd
Contact:0512-80972173
Address:21st Building, No.369 Lushan Rd, New District Suzhou China 215129
website:http://www.eastarchem.com/
Contact:1-800-898-2436
Address:1215 K Street, STE 1700
Doi:10.1016/j.bmc.2014.03.012
(2014)Doi:10.1007/s11164-014-1639-0
(2014)Doi:10.1002/ejoc.201301374
(2014)Doi:10.1002/ejoc.201301340
(2014)Doi:10.1016/j.ejmech.2014.04.017
(2014)Doi:10.1002/anie.201310000
(2014)
