Synthesis, Molecular Structure and Reactivity of cis-1,κN)> a Compound displaying an Unusual η1 Arene-Palladium Interaction

DOI: 10.1039/DT9940003143

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3143 - 3148 (1994)

Update date:2022-08-05

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Authors:

Falvello, Larry R.

Fornies, Juan

Navarro, Rafael

Sicilia, Violeta

Tomas, Milagros

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Article abstract of DOI:10.1039/DT9940003143

The reaction between cis- (thf = tetrahydrofuran) and benzyldimethylamine rendered cis-1,κN)> 1, a four-co-ordinate compound containing as unusual η¹ arene-palladium interaction with the benzyldimethylamine acting as a bidentate chelating ligand.Complex 1 reacts with acetone, acetonitrile, dimethyl sulfoxide or CO (L) to yield cis- 2-5 respectively, which do not have a η¹ arene-palladium interaction.The reaction of 1 with Br(1-) or SPMe2Ph (L') (molar ratio 1:1) produced the complete displacement of the amine and the formation of <(F5C6)2Pd(μ-L')2Pd(C6F5)2>(n-) (n = 2 or 0), and with Cl(1-) (molar ratio 1:1) a mixture of complexes is formed.The crystal structures of compounds 1 and 2 have been determined.

Full text of DOI:10.1039/DT9940003143

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