Stereoselective synthesis of dimethylrobustadials

DOI: 10.1021/jo00101a031

Source and publish data:

Journal of Organic Chemistry p. 6697 - 6702 (1994)

Update date:2022-08-04

Topics: Organic compounds Catalyst Stereochemistry Stereoselective synthesis Stereoselectivity Chemical Reaction Experimental conditions

Authors:

Majewski

Irvine Irvine

Bantle Bantle

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Article abstract of DOI:10.1021/jo00101a031

A stereoselective synthesis of the methyl ethers of robustadials A and B (24) is described. The crucial step is the amine-catalyzed cyclization of the enone 8b which leads to the products 9b and 10b with high diastereoselectivity. The choice of the amine

Full text of DOI:10.1021/jo00101a031

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