39830-44-9Relevant academic research and scientific papers
Optically Active Trifluoromethylcarbinols as Chiral Solvating Agents for Asymmetric Transformations at a Ring-Nitrogen Atom. Synthesis of Optically Active N-Chloroaziridines and Stereochemical Aspects of Chiral Solvent-Aziridine Solute Complexes
Bucciarelli, Maria,Forni, Arrigo,Moretti, Irene,Torre, Giovanni
, p. 2640 - 2644 (1983)
Chlorination at a ring nitrogen of an aziridine substrate, when carried out with tert-butyl hypochlorite or N-chlorosuccinimide in the presence of chiral trifluoromethylcarbinols, affords optically active N-chloroaziridines.Synthesis of chiral N-chloroazi
Absolute Configuration of a Chiral N-Chloroaziridine with Molecular Asymmetry due solely to a Trivalent Nitrogen Atom. X-Ray Structure of (R)-(-)-1-Chloro-2,2-diphenylaziridine
Brueckner, Sergio,Forni, Arrigo,Moretti, Irene,Torre, Giovanni
, p. 1218 - 1219 (1982)
X-Ray analysis of the crystalline optically active 1-chloro-2,2-diphenylaziridine, obtained by chlorination of 2,2-diphenylaziridine with t-butyl hypochlorite in the presence of a chiral trifluoro-alcohol, followed by fractional crystallization of the cru
Relationships between Solid-state Structures of Enantiomers and the Corresponding Racemic Compounds in Small Ring Derivatives. Comparison of Crystal Structures and Solid-state Properties of (R)-(-)- and Racemic 1-Chloro-2,2-diphenylaziridine. Solvent Effe
Forni, Arrigo,Moretti, Irene,Torre, Giovanni,Brueckner, Sergio,Malpezzi, Luciana,Silvestro, Giuseppe Di
, p. 791 - 798 (2007/10/02)
The synthesis of highly optically pure N-chloro-2,2-diphenylaziridine, in a crystalline form and sufficiently stable at room temperature, has enabled the study and the comparison to be carried out of the solid-state properties (e.g., the m.p. phase diagra
